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5.5.3.3. Conditioner chemie

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Auteur : David Bogert

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7 minuten
Difficulty : Level 8

Excerpt :

The chemistry of aquarium water conditioners is very simple and straightforward.
5.5.3.3. Conditioner chemie
5.5.3.3. Conditioner chemie

All conditioner’s use the same basic chemistry to do the same thing. They all have some form of a sulfite (SO₃, one sulfur atom with three oxygen atoms) that oxidizes in the presence of chlorine to a sulfate (SO₄, one sulfur atom and four oxygen atoms). The reaction turns the toxic chlorine into harmless table salt (chloride). ALL conditioners do this and ONLY this.

While virtually all of these products now claim to neutralize or temporarily “detoxify” ammonia, nitrite and nitrate, NONE of them do that. All of them are just spouting marketing hype.  Note that while as I have pointed out Mother Nature can be very flexible and unpredictable in many areas related to fishkeeping, this isn’t one of those areas. The above is based on firmly-established, indisputable facts of chemistry.

Mijn aanbeveling met conditioners is eenvoudig:

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Buy ONLY Conditioners that say “Sodium Thiosulfate” on the Bottle in the Ingredients List. Then use 5X the Recommended Dosage.

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When I used to have chlorinated water for a 60 gallon tank 50% water change I would take the amount of thiosulfate conditioner which would, per the bottle, condition 30×5 or 150 gallons of water and add it to the 30 gallons that was left in the aquarium after draining. Thiosulfate is just very harmless, even at a 10x concentration. Then I would refill the tank with water above 70 degrees. Easy.

Buccochromis atritaeniatus
Buccochromis atritaeniatus
Thiosulfate “Conditioners”

Many off-the-shelf chlorine neutralizers (API Conditioner, Wardley’s ChlorOut, Aqueon Conditioner, Weco Dechlor, Marineland Conditioner, Mardel’s MarChlor, Drs. Foster & Smith Chlorine Neutralizer) list as their active ingredient sodium thiosulfate. This is a very safe chemical to use with fish.

The actual reaction of chlorine with sodium thiosulfate is:

3 Na₂S₂O₃ + 4 Cl₂ + 5 H₂O -> 2 NaHSO₄ + 8 HCl

Alternatively this can be written:

Na₂S₂O₃ + 4 NaClO +H₂O –> 2 NaHSO₄ + 4 NaCl

The end result of this equation is simply hydrochloric acid, sodium hydrogen sulfate or sodium chloride in tiny quantities so small they can be ignored.

With chloramine this equation becomes:

Na₂S₂O₃ + 4 NH₂Cl + 5 H₂O -> 2 NaHSO₄ + 4 NH₄Cl

The end result of this equation is sodium hydrogen sulfate and ammonium chloride in quantities so small they can be ignored.

Symphysodon aequifasciatus – Discusvis
Symphysodon aequifasciatus – Discusvis
SeaChem Prime and SeaChem Safe

SeaChem Prime and SeaChem Safe are sodium dithionite. Sodium dithionite removes chlorine because it is a mild reducing agent and chlorine gas is a strong oxidizing agent. It is exactly equivalent to sodium thiosulfate as a remover of chlorine, no better, no worse.

In water sodium dithionite decomposes to sodium thiosulfate and sulfurous acid:

2 Na₂S₂O₄ + H₂O = Na₂S₂O₃ + 2 H₂SO₃

This sulfurous acid is the “sewage” smell you can get with Safe and Prime. These two chemical species then react with the chlorine to produce table salt

2Na₂S₂O₄ + H₂O –> Na₂S₂O₃ + 2NaHSO₃

Na₂S₂O₃ + 4NaClO + H₂O –> 2NaHSO₄ + 4NaCl

2NaHSO₃ + 2NaClO –> 2NaHSO₄ + 2NaCl

2H₂SO₃ + 4NaClO + H₂O -> 3 H₂SO₄ + 4 NaCl

Using Prime and Safe will work very well to neutralize chlorine and chloramine, just like the thiosulfate conditioners. Using Seachem Prime and Seachem Safe conditioners poses no hazards to one’s fish.

But Seachem makes a lot of deceptive or false claims about the abilities of their very overpriced Prime and Safe products (“Prime detoxifies ammonia, nitrite and nitrate“). These claims probably do not harm the fish. But the claims need to be called out for the deception that they are. We do that in the following link:

5.5.3.2.  Marketing Hype for Prime and Safe

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Image of a tropical fish Flowerhorn Cichlid Hybrid
Flowerhorn Cichlid Hybrid
Sulfinate Conditioners

Another chemical which is used to remove chlorine is sodium hydroxymethanesulfinate (Tetra AquaSafe Plus, Kordon AmQuel, Kordon AmQuel plus, API Aqua-Essential, ClorAm-X, Hikari Ultimate, API Stress Coat +). Sodium hydroxymethanesulfinate (used to be called “Rongalite”) does remove chlorine via the equation:

HO-CH₂-SO₃Na + Cl₂ + H₂O = HO-CH₂-SO₄Na +2HCl.

This is exactly the same as the sodium thiosulfate and sodium dithionite, no difference in effectiveness or in capabilities. And this product categorically does not remove ammonia or “detoxify” it for 24 hours. That’s marketing hype (see the link below for chemistry). The HO-CH₂-SO₄Na in this equation will go rather rapidly to a solution of formaldehyde and sodium sulfite, especially in acid water. The formaldehyde can kill fish. So these products need to be used with more caution than other water conditioners.

5.5.3.1. “Ammonia Detoxifying” Claims

These “sodium hydroxymethanesulfinate” products are made by taking sodium dithionite and adding differing amounts of formaldehyde and sodium bicarbonate. Sometimes other sulfite salts like sodium bisulfite are added. These additions do not change the chemistry one bit.

Tyrannochromis maculiceps
Tyrannochromis maculiceps

Formaldehyde stabilizes the dithionite by the formation of a compound called “Rongalite” or sodium hydroxymethanesulfinate via the following reaction.

Na₂S₂O₄ + 2 CH₂O + H₂O → HO-CH₂-SO₃Na + HO-CH₂-SO₂Na

The formaldehyde is typically added in excess to prevent decomposition of the product. The sodium hydroxymethanesulfinate will also revert to formaldehyde when its neutralizes chlorine. This formaldehyde is why one cannot excessively overdose these products or add it to formalin based medications. A formalin overdose can be made.

Because the conditioners that do not use the sodium thiosulfate chemistry rarely identify what chemical is in them we recommend that all products that do not have sodium thiosulfate on the label be treated as though they have formalin in them.

Heros efasciatus Rio Araguaia
Heros efasciatus Rio Araguaia
Toxicity of Sodium Thiosulfate

I’m constantly getting comments like “a 5x concentration of sodium thiosulfate will remove all the oxygen from the water and suffocate the fish“. The concentration in ppm of sodium thiosulfate in the water at 5x is about 13 ppm.

There are several pertinent studies:

  • The mosquito fish, Gambusia affinis, died at a very high concentration of 24,000 ppm sodium thiosulfate, close to the concentration of salt in sea water (“Toxicity to Gambusia affinis of Certain Pure Chemicals in Turbid Waters”, Wallen, et al.,1957).
  • The flatworm Polycelis nigra was found to die at 8400 ppm sodium thiosulfate (“A Study in the Relative Toxicity of Anions with Polycelis Nigra (Planarian) as Test Animal.” Jones, 1941).
  • The water flea Daphnia magna was found to die at a level of 520 ppm sodium thiosulfate (“The Toxicity Thresholds of Various Sodium Salts Determined by the Use of Daphnia magna”, Anderson, 1946).

Genoeg gezegd.

picture of tropical fish Pterophyllum scalare, Angelfish
Pterophyllum scalare, maanvissen
Conditioners do not Deplete Oxygen Levels

One of the myths of conditioners is that conditioners remove oxygen from the aquarium water and thus aeration is needed and one must never overdose. A half used bottle of conditioner has a sizable amount of oxygen in it in the air above the fluid. Yet it will take two to five years for half of the conditioner to be oxidized. And this is even if the bottle is opened and closed once a month for those two and a half years. That’s a lot of oxygen available. Yet the oxygen doesn’t rapidly combine with the sulfite (SO₃) in its various forms to neutralize it.

For instance, to get sodium thiosulfate to reduce oxygen one has to heat the pure salt to over 120 degrees C. In a 23 degree aquarium there will be NO reduction going on.

The key here is that oxygen is a much weaker oxidizer than is chlorine. So conditioner categorically does not remove oxygen from an aquarium and can be overdosed without fear of removing the oxygen from the water.

If you overdose one of the formaldehyde based water conditioners with an excess of formaldehyde in them, you can possibly damage the gills of the fish and they will “pant” at the surface of the water. This is due to gill damage, not low oxygen levels.

Protomelas spilonotus Tanzania
Protomelas spilonotus Tanzania
Further Reading

Er zijn enkele aquarium hobbyisten die geïnteresseerd zijn om diep in de wetenschap en de berekeningen achter alle aspecten van de hobby te duiken. Voor degenen die daartoe geneigd zijn, is het volgende van belang:

5.3.3. Water Conditioners

5.5.3.1. “Ammonia Detoxifying” Claims

5.5.3.2. Seachem Prime and Safe

5.5.3.4. Water Conditioner Cost

5.5.3.5. Water Conditioner Testing

5.5.3.6. Review Of Water Conditioners

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